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cyberduck - ftp/ssh/etc
Burn - to burn images/cd/dvd/etc
VLC - dopest media player on pretty much ANY platform
Transmission - Torrents
Colloquy - IRC
What else would you need? Other than the usual shit that has already been stated like PS and MS Office...
If you're worried about making the switch over to OSX even smoother, you can partition your hdd and run windows 7 or whatever you please... There are a few different options to doing this.
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